CobaltMaghrebV1, France, Analysis, bibRecord, 000054

Chlorido(pyridine-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloroform hemisolvate

Identifieur interne : 000054 ( France/Analysis ); précédent : 000053; suivant : 000055

Chlorido(pyridine-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloroform hemisolvate

Auteurs : Yassin Belghith [Tunisie] ; Jean-Claude Daran [France] ; Habib Nasri [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.

RBID : PMC:3414153

Abstract

In the title complex, [CoCl(C₄₄H₂₈N₄)(C₅H₅N)]·0.5CHCl₃ or [Co^III(TPP)Cl(py)]·0.5CHCl₃ (where TPP is the dianion of tetraphenylporphyrin and py is pyridine), the average equatorial cobalt–pyrrole N atom bond length (Co—N_p) is 1.958 (7) Å and the axial Co—Cl and Co—N_py distances are 2.2339 (6) and 1.9898 (17) Å, respectively. The tetraphenylporphyrinate dianion exhibits an important nonplanar conformation with major ruffling and saddling distortions. In the crystal, molecules are linked via weak C—H⋯π interactions. In the difference Fourier map, a region of highly disordered electron density was estimated using the SQUEEZE routine [PLATON; Spek (2009 ▶), Acta Cryst. D65, 148–155] to be equivalent to one half-molecule of CHCl₃ per molecule of the complex.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414153

DOI: 10.1107/S1600536812032564
PubMed: 22904760
PubMed Central: 3414153

Affiliations:

France, Tunisie

Links to Exploration step

PMC:3414153

Le document en format XML

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)(5,10,15,20-tetraphenylporphyrinato-κ<sup>4</sup>
<italic>N</italic>
)cobalt(III) chloroform hemisolvate</title>
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<italic>N</italic>
)cobalt(III) chloroform hemisolvate</title>
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<front><div type="abstract" xml:lang="en"><p>In the title complex, [CoCl(C<sub>44</sub>
H<sub>28</sub>
N<sub>4</sub>
)(C<sub>5</sub>
H<sub>5</sub>
N)]·0.5CHCl<sub>3</sub>
 or [Co<sup>III</sup>
(TPP)Cl(py)]·0.5CHCl<sub>3</sub>
 (where TPP is the dianion of tetraphenylporphyrin and py is pyridine), the average equatorial cobalt–pyrrole N atom bond length (Co—N<sub>p</sub>
) is 1.958 (7) Å and the axial Co—Cl and Co—N<sub>py</sub>
 distances are 2.2339 (6) and 1.9898 (17) Å, respectively. The tetraphenylporphyrinate dianion exhibits an important nonplanar conformation with major ruffling and saddling distortions. In the crystal, molecules are linked <italic>via</italic>
 weak C—H⋯π interactions. In the difference Fourier map, a region of highly disordered electron density was estimated using the SQUEEZE routine [<italic>PLATON</italic>
; Spek (2009<xref ref-type="bibr" rid="bb20"> ▶</xref>
), <italic>Acta Cryst.</italic>
 D<bold>65</bold>
, 148–155] to be equivalent to one half-molecule of CHCl<sub>3</sub>
 per molecule of the complex.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Chlorido(pyridine-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloroform hemisolvate

Chlorido(pyridine-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloroform hemisolvate

Source :

Abstract

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Serveur d'exploration sur le cobalt au Maghreb

Chlorido(pyridine-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ4N)cobalt(III) chloro­form hemisolvate

Chlorido(pyridine-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ4N)cobalt(III) chloro­form hemisolvate

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Abstract

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Chlorido(pyridine-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloroform hemisolvate

Chlorido(pyridine-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobalt(III) chloroform hemisolvate